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Tetraarsenic tetrasulfide : ウィキペディア英語版
Realgar

Realgar, α-As4S4, is an arsenic sulfide mineral, also known as "ruby sulphur" or "ruby of arsenic". It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related mineral, orpiment (As2S3). It is orange-red in colour, melts at 320 °C, and burns with a bluish flame releasing fumes of arsenic and sulfur. Realgar is soft with a Mohs hardness of 1.5 to 2 and has a specific gravity of 3.5. Its streak is orange colored. It is trimorphous with alacranite and pararealgar.〔
Its name comes from the Arabic ''rahj al-ġār'' (, "powder of the mine"), via Catalan and Medieval Latin, and its earliest record in English is in the 1390s.
== Occurrence ==
Realgar most commonly occurs as a low-temperature hydrothermal vein mineral associated with other arsenic and antimony minerals. It also occurs as volcanic sublimations and in hot spring deposits. It occurs in association with orpiment, arsenolite, calcite and barite.〔
It is found with lead, silver and gold ores in Hungary, Bohemia and Saxony. In the US it occurs notably in Mercur, Utah; Manhattan, Nevada and in the geyser deposits of Yellowstone National Park.〔
It is commonly held that after a long period of exposure to light realgar changes form to a yellow powder known as pararealgar (β-As4S4). It was once thought that this powder was the yellow sulfide orpiment, but has been recently shown to be a distinct chemical compound.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Realgar」の詳細全文を読む



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